Copper ii trifluoropentanedionate - Names and Identifiers
Name | bis(1,1,1-trifluoropentane-2,4-dionato-O,O')copper
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Synonyms | TRIFLUOROACETYL ACETONE, CU(II) Copper ii trifluoropentanedionate Copper bis(trifluoroacetylacetonate) Copper 1,1,1-trifluoroacetylacetonate Cupric 1,1,1-trifluoroacetylacetonate TRIFLUOROACETYLACETONO COPPER(II) SALT BIS(TRIFLUORO-2,4-PENTANEDIONATO)COPPER(II) Copper bis(1,1,1-trifluoro-2,4-pentanedionate) Copper, bis(1,1,1-trifluoro-2,4-pentanedionato)- bis(1,1,1-trifluoropentane-2,4-dionato-O,O')copper Bis(1,1,1-trifluoropentane-2,4-dionato-O,O')copper Copper, bis(1,1,1-trifluoro-2,4-pentanedionato-O,O')- copper(2+) bis[(2Z)-1,1,1-trifluoro-4-oxopent-2-en-2-olate]
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CAS | 14324-82-4
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EINECS | 238-271-4 |
InChI | InChI=1/2C5H5F3O2.Cu/c2*1-3(9)2-4(10)5(6,7)8;/h2*2,10H,1H3;/q;;+2/p-2/b2*4-2- |
InChIKey | GZVJAFMHAGQIEB-BGHCZBHZSA-L |
Copper ii trifluoropentanedionate - Physico-chemical Properties
Molecular Formula | C10H8CuF6O4
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Molar Mass | 369.7 |
Density | 0.721 g/cm3 |
Melting Point | 198-199 °C (lit.) |
Boling Point | 260°C |
Flash Point | 260°C |
Vapor Presure | 0.108mmHg at 25°C |
Appearance | Powder |
Color | purple |
Storage Condition | 2-8℃ |
Sensitive | 4: no reaction with water under neutral conditions |
MDL | MFCD00042511 |
Copper ii trifluoropentanedionate - Risk and Safety
Hazard Symbols | T - Toxic
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Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | S22 - Do not breathe dust.
S24/25 - Avoid contact with skin and eyes.
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WGK Germany | 3 |
TSCA | No |
Hazard Note | Toxic |
Copper ii trifluoropentanedionate - Introduction
Copper (I) 1,1, 1-trifluoro-2, 4-acetylacetonate, also known as Cu(DFA)F, is an organometallic compound. The following is a description of its nature, use, preparation and safety information:
Nature:
Copper (I) 1,1, 1-trifluoro-2, 4-acetylacetonate is a colorless to pale yellow solid. It has relatively high thermal stability and solubility, and is stable under light.
Use:
The compound is commonly used in organic thin film solar cells in organic photovoltaic (organic photovoltaic) devices. As a complexing agent, Cu(DFA)F can provide conductivity for charge pathways and charge injection.
Preparation Method:
A method for preparing copper (I) 1,1, 1-trifluoro-2, 4-acetylacetonate is to react 2,4-hexanedione and trifluoroacetyl formate (TFEM) with cuprous chloride (CuCl) in dichloromethane. The product of this reaction can be filtered and washed to give pure copper (I) 1,1, 1-trifluoro-2, 4-acetylacetonate.
Safety Information:
The safety information of 1,1, 1-trifluoro-2, 4-acetylacetonate copper (I) requires further research and evaluation. Because this is an organometallic compound, it is necessary to follow laboratory safety procedures and necessary personal protective measures when using, storing and handling.
Last Update:2024-04-09 02:00:42